MCQ
Two compounds $A$ and $B$ with same molecular formula $\left( C _{3} H _{6} O \right)$ undergo Grignard's reaction with methylmagnesium bromide to give products $C$ and $D$. products $C$ and $D$ show following chemical tests.
| Test | $C$ | $D$ |
| Ceric ammonium nitrate Test | Positive | positive |
| Lucas Test | Turbidity obtained after five minutes | Turbidity obtained immediately |
| Iodoform Test | Positive | Negative |
$C$ and $D$ respectively are
- A$C = {H_3}C - \begin{array}{*{20}{c}} {C{H_3}\,\,\,\,\,\,\,\,} \\ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\ {C - OH} \\ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\ {C{H_3\,\,\,\,\,\,\,\,}} \end{array}$
$\begin{array}{*{20}{c}} {D = {H_3}C - C{H_2} - CH - C{H_3}} \\ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH} \end{array}$
- B$C = H _{3} C - CH _{2}- C H _{2}- CH _{2}- OH$
$D = {H_3}C - \begin{array}{*{20}{c}} {C{H_3}\,\,\,\,\,} \\ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\ {C - OH} \\ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\ {C{H_3}\,\,\,\,\,} \end{array}$
- ✓$\begin{array}{*{20}{c}} {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH} \\ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\ {C = {H_3}C - C{H_2} - CH - C{H_3}} \end{array}$
$D = {H_3}C - \begin{array}{*{20}{c}} {C{H_3}\,\,\,\,\,} \\ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\ {C - OH} \\ |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\ {C{H_3}\,\,\,\,\,} \end{array}$
- D$C = H _{3} C - CH _{2}- CH _{2}- CH _{2}- OH$
$\begin{array}{*{20}{c}} {D = {H_3}C - C{H_2} - CH - C{H_3}} \\ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH} \end{array}$
