MCQ
Two statements are given $-$ one labelled
Assertion $(A)$ and the other labelled
Reason $(R)$. Select the correct answer to these questions from the codes $(a), (b), (c)$ and $(d)$ as given below:
Assertion $(A):$ In a homologous series of alcohols, the formula for the second member is $C _2 H _5 OH$ and the third member is $C _3 H _7 OH$.
Reason$(R):$ The difference between the molecular masses of the two consecutive members of a homologous series is $144 .$
  • A
    Both $A$ and $R$ are true, and $R$ is correct explanation of the assertion.
  • B
    Both $A$ and $R$ are true, but $R$ is not the correct explanation of the assertion.
  • $A$ is true, but $R$ is false.
  • D
    $A$ is false, but $R$ is true.

Answer

Correct option: C.
$A$ is true, but $R$ is false.

A homologous series is a series of organic compounds that contains identical functional group and differs only in the length of the carbon chain in the compound.
The general formula for homologous series for alcohols is $C ( n ) H (2 n +1) OH$, where $n$ is a natural number.
Substituting $n=2$ and $n=3$ we get $C _2 H _5 OH$ and $C _3 H _7 OH$ respectively, which verifies the assertion made.
The two consecutive members of the homologous series varies only by a $CH _2$ group, hence the difference in molecular mass of two consecutive members is equal to $14 .$

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