MCQ
Unlike phenol, 2,4-dinitrophenol is soluble in sodium carbonate solution in water because?
  • A
    Presence of two -NO2​ groups in the ring makes 2, 4 - dinitrophenol a stronger acid than phenol.
  • B
    Presence of two -NO2​ groups in the ring makes 2, 4 - dinitrophenol a weaker acid than phenol.
  • C
    presence of two -NO2​ groups make the hydrogen bonding easier, making 2, 4-dinitrophenol soluble.
  • D
    Nitro group reacts with Na2​CO3​ while -OH group does not.

Answer

  1. Presence of two -NO2​ groups in the ring makes 2, 4 - dinitrophenol a stronger acid than phenol.

Explanation:

Presence of two electron withdrawing −No2​ groups in the ring makes 2,4-dinitrophenol a stronger acid than phenol. Hence it react with aqueous Na2​CO3​ solution to form sodium salt thus making it soluble in Na2​CO3​.

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