Question
What are Carbohydrates? How are they classified?

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In which of the following pairs will more electric current flow and why?
(a) KCl solution $25^{\circ} C$ and KCl solution at $50^{\circ} C$.
(b) $0.2 \quad M \quad CH _3 COOH$ solution and 2 M $CH _3 COOH$ solution.
(c) $NH _4 OH$ solution at $25^{\circ} C$ and at wire at $50^{\circ} C$.
(d) Al wire at $25^{\circ} C$ and Al wire at $50^{\circ} C$.
Give reasons for the following:
  1. Transition metals form alloys.
  2. $\ce{Mn_2O_3}$ is basic whereas $\ce{Mn_2O_7}$ is acidic.
  3. $\ce{Eu^{2+}} $ is a strong reducing agent.
Explain electrolysis of concentration aqueous solution of $\text{NaCl}$
  1. How would you account for the following:
  1. Actinoid contraction is greater than lanthanoid contraction.
  2. Transition metals form coloured compounds.
  1. Complete the following equation:
$\text{2MnO}_{4}^{-}+\text{6H}^{+}+\text{5NO}_{2}^{-}\rightarrow$
A special thermometer (Beckmann thermometer) is used to determine molecular weight by freezing point depression method instead of ordinary thermometer. Why?
Write down the number of 3d electrons in each of the following ions :
$Ti ^{2+}, V ^{2+}, Cr ^{3+}, Mn ^{2+}, Fe ^{2+}, Fe ^{3+}, Co ^{2+}, Ni ^{2+}, Cu ^{2+}$.
Indicate how would you expect the five 3d orbitals to be occupied for these hydrated ions (octahedral).
Chromium metal can be plated out from an acidic solution containing $CrO_3$ according to the following equation:
$\text{CrO}_3(\text{aq})+6\text{H}^+(\text{aq})+6\text{e}^-\xrightarrow{ \ \ \ \ \ \ \ \ \ \ \ }\text{Cr(s)}+3\text{H}_2\text{O}$
Calculate:
  1. How many grams of chromium will be plated out by $24,000$ coulombs.
  2. How long will it take to plate out $1.5g$ of chromium by using $12.5A$ current?
$($At. mass of $Cr = 52).$
What happens when
  1. Ethyl chloride is treated with $\ce{NaI}$ in the presence of acetone,
  2. Chlorobenzene is treated with $\ce{Na}$ metal in the presence of dry ether,
  3. Methyl chloride is treated with $\ce{KNO_2}$?
Write chemical equations in support of your answer.
Write the reactions and conditions for the following conversions:
i. 2-Propanone into 2-methyl-2-Proponal
ii. n-Propyl alcohol into hexane