Maharashtra BoardEnglish MediumSTD 12 ScienceChemistryIntroduction to Polymer Chemistry4 Marks
Question
What is LDP? How is it prepared? Give its properties and uses.
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Answer
LDP means low-density polyethene. LDP is obtained by polymerization of ethylene under high pressure $(1000-2000 atm )$ and temperature $(350-570 K )$ in presence of traces of $O _2$ or peroxide as initiator.
The mechanism of this reaction involves free radical addition and H-atom abstraction. The latter results in branching. As a result the chains are loosely held and the polymer has low density.
Properties of LDP :
LDP films are extremely flexible, but tough chemically inert and moisture resistant.
It is poor conductor of electricity with melting point $110^{\circ} C$.
Uses of LDP :
LDP is mainly used in preparation of pipes for agriculture, irrigation, domestic water line connections as well as insulation to electric cables.
It is also used in submarine cable insulation.
It is used in producing extruded films, sheets, mainly for packaging and household uses like in preparation of squeeze bottles, attractive containers, etc.
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