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What is peptide linkage? How is tripeptide formed?

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What is the value of $\Delta$ Ssurr for the following reaction at $298 K$ -
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Given that: $\Delta G^{\circ}=2879 KJ mol ^{-1}$
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What are the characteristics of rate constant?
In the reaction, $PCl _{5( g )} \rightarrow PCl _{3( g )}+ Cl _{2( g )}$, at a particular moment, the rate of disappearance of $PCl _5$ is $0.015 Ms ^{-1}$. What are the rates of formation of $PCl _3$ and $Cl _2$ ?
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