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What is Solubility? Explain Solubility of a solid in a liquid.

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Gabriel phthalimide synthesis.
(i) Give the structure of haloalkane having five carbon by which optical isomerism is shown.
(ii) Which type of isomerism is present in 1-chloro butane and 1-chloro-2-methyl propane.
(iii) Write the position isomers of the compound having molecular formula $C _4 H _9 Cl$, which have straight chain.
A copper-silver cell is set up. The copper ion concentration in it is 0.10 M. The concentration of silver ion is not known. The cell potential measured 0.422 V. Determine the concentration of silver ion in the cell.
$\text{Given: E}^{o}_{\text{Ag}^{+}/\text{Ag}}=+0.80\text{V},\text{E}^{o}_{\text{Cu}^{2+}/\text{Cu}}=+0.34\text{V}.$
How would you account for the following? 
  1. Many of the transition elements are known to form interstitial compounds.
  2. The metallic radii of the third (5d) series of transition metals are virtually the same as those of the corresponding group members of the second (4d) series.
  3. Lanthanoids form primarily +3 ions, while the actinoids usually have higher oxidation states in their compounds, +4 or even +6 being typical.
  1. Which one of the following is a disaccharide: Starch, Maltose, Fructose, Glucose?
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  3. Write the name of vitamin whose deficiency causes bone deformities in children.
Name two complexes which are used in medicines.
Determine the formula for the half life of a first order reaction and prove that the half life of a first order reaction does not depends on the initial concentration of the reactant.
Write short note on tetra chloromethane (CCL4) ### Write short note on Carbon tetra chloride.
What are Carbohydrates? How are they classified?
i. Write the mechanism of the following SN1 reaction:
$\left(\mathrm{CH}_3\right)_3 \mathrm{C}-\mathrm{Br} \xrightarrow{A q . \mathrm{NaOH}}\left(\mathrm{CH}_3\right)_3 \mathrm{C}-\mathrm{OH}+\mathrm{NaBr}$
ii. Write the equation for the preparation of 2-methyl-2-methoxypropane by Williamson synthesis.