What is the expected order of reactivity of the following compounds in electrophilic chlorination $(Cl_2 + FeCl_3)$?
(more reactive $>$ less reactive)
A$I > II > III > IV$
B$IV > III > II > I$
C$III > I > IV > II$
D$II > III > I > I V$
Medium
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D$II > III > I > I V$
d $(d)$ Reaction with respect to activating group.
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What is major product of following reaction? $\begin{array}{*{20}{c}}
{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{{C_2}{H_5} - C - N{H_2}\xrightarrow[{B{r_2}}]{{KOH}}A\xrightarrow[{KOH}]{{CHC{l_3}}}}
\end{array}$ Major Product
Assertion : Acylation of amines gives a monosubstituted product whereas alkylation of amines gives polysubstituted product.
Reason : Acyl group sterically hinders the approach of further acyl groups