STD 12 - 7. Alcohol, phenol and ethers — JEE STD 11 Science — Question

$[ R =$ gas constant, $F =$ Faraday constant, $T =$ Temperature $]$

$(A)$ For the reaction, $M (s)+2 H ^{+}(a q) \rightarrow H _2(g)+ M ^{2+}(a q)$, if $\frac{ dE _{c o l l}}{ dT }=\frac{ R }{ F }$, then the entropy change of the reaction is $R$ (assume that entropy and internal energy changes are temperature independent).

$(B)$ The cell reaction, $Pt (s) \mid H _2(g, 1$ bar $)\left| H ^{+}(a q, 0.01 M ) \| H ^{+}(a q, 0.1 M )\right| H _2(g, 1 bar ) \mid Pt (s)$, is an entropy driven process.

$(C)$ For racemization of an optically active compound, $\Delta S >0$.

$(D)$ $\Delta S >0$, for $\left[ Ni \left( H _2 O \right)_6\right]^{2+}+3$ en $\rightarrow\left[ Ni ( en )_3\right]^{2+}+6 H _2 O$ (where en $=$ ethylenediamine).

$(a)\,N{H_4}N{O_2}\xrightarrow{\Delta }{N_2} + {H_2}O$

$(b)\,N{H_4}N{O_3}\xrightarrow{\Delta }{N_2}O + {H_2}O$

$(c)\,N{a_2}C{O_3}\xrightarrow{\Delta }N{a_2}O + C{O_2}$

$(d)\,N{H_4}Cl\xrightarrow{\Delta }N{H_3} + HCl$

(Round off to the NearestInteger)

[Use:Atomicmasses:$Na:23.0\,u \mathrm{O}: 16.0 \,\mathrm{u} \quad \mathrm{H}: 1.0 \,\mathrm{u}$, Density of $\mathrm{H}_{2} \mathrm{O}: 1.0 \,\mathrm{~g} \,\mathrm{~cm}^{-3}$ ]