When ethanol is mixed with ammonia and passed over alumina the compound formed is
AIPMT 1990, Medium
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Statement $II:$ Primary aromatic amines react with $HNO _{2}$ to form diazonium salts which are stable even above $300 \,K$.
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{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{Ph - C - OH\xrightarrow[\Delta ]{{N{H_3}}}(A){\mkern 1mu} \xrightarrow[{KOH}]{{B{r_2}}}(B),{\mkern 1mu} }
\end{array}{\mkern 1mu} {\mkern 1mu}$ product $B$ is