MCQ
When glycerol is heated with $KHS{O_4}$ it gives
  • A
    $C{H_2} = CH - C{H_3}$
  • B
    $C{H_2} = CH - C{H_2}OH$
  • $C{H_2} = CH - CHO$
  • D
    $C{H_2} = C = C{H_2}$

Answer

Correct option: C.
$C{H_2} = CH - CHO$
c
$\underset{Glycerol}{\mathop{\begin{matrix}
   \begin{matrix}
   \begin{matrix}
   H  \\
   |  \\
   \,\,\,\,H-C-OH  \\
\end{matrix}  \\
   |  \\
   HO-C-H\,\,\,\,  \\
   |  \\
\end{matrix}  \\
   H-C-H  \\
   |  \\
   \,\,\,\,\,OH  \\
\end{matrix}}}$  $\xrightarrow{KHS{{O}_{4}}}$  $\underset{Unstable}{\mathop{\begin{matrix}
   \begin{matrix}
   \begin{matrix}
   \,\,\,H\,\,\,\,\,\,\,  \\
   \,\,\,|\,\,\,\,\,\,\,  \\
   H-C\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
  \,\, \,||\,\,\,\,\,\,\,\,\,  \\
   \,\,C\,\,\,\,\,\,\,\,\,  \\
   |\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
   \,\,\,\,C-H  \\
   |\,\,\,\,\,\,\,\,\,\,  \\
   OH\,\,\,\,  \\ 
\end{matrix}}}\,$  $\to $ $\underset{Unstable}{\mathop{\begin{matrix}
   \begin{matrix}
   \begin{matrix}
   \,\,\,H\,\,\,\,\,\,\,  \\
   \,\,\,|\,\,\,\,\,\,\,  \\
   H-C\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
   \,\,\,||\,\,\,\,\,\,\,\,\,  \\
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C-H\,\,\,\,\,\,\,\,\,  \\
  \,\,\,||\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
   \,\,\,\,\,C-H  \\
   \,\,\,||\,\,\,\,\,\,\,\,\,\,  \\
   \,\,O\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}}}\,$  Or  $\underset{Acrolein}{\mathop{\begin{matrix}
   \begin{matrix}
   C{{H}_{2}}\,\,  \\
   ||\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
   CH\,\,\,\,  \\
   |\,\,\,\,\,\,\,\,\,  \\
   CHO  \\
\end{matrix}}}\,$

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