MCQ
When $SO_2$ is passed through a solution of $H_2S$ in water :-
  • A
    Sulphuric acid is formed
  • B
    A clear solution is formed
  • A sulphur is precipitated
  • D
    No change observed

Answer

Correct option: C.
A sulphur is precipitated
c
Peroxodisulphuric acid $\left(\mathrm{H}_{2} \mathrm{S}_{2} \mathrm{O}_{8}\right)$

$\,\begin{array}{*{20}{c}}
  {\begin{array}{*{20}{c}}
  {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} 
\end{array}} \\ 
  {HO - S - O - O - S - OH} \\ 
  {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} 
\end{array}\,$  $+2 \mathrm{HOH} \rightarrow 2 \mathrm{H}_{2} \mathrm{SO}_{4}+\mathrm{H}_{2} \mathrm{O}_{2}$

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