MCQ
Which is correct for halogen w.r.t. electron affinity :
  • $F > I$
  • B
    $Br > F$
  • C
    $F > Cl$
  • D
    $Br > Cl$

Answer

Correct option: A.
$F > I$
(a) $F > I$
Explanation : The correct order of Electron gain enthalpy of halogen family is, $Cl > F > Br > I$. The reason for this is that the size of the fluorine atom is very small. So, when an electron is added in the fluorine atom it will suffer more electronegativity as all the electrons will be very close to each other and hence the electron gain enthalpy of chlorine is more negative than that of fluorine.

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