which is more reactive towards $\ce{S_N1}$ reaction and why?
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$\ce{CH_3CH_2CH(Cl)CH_3}$; secondary halide $/2^0$ carbocation is more stable.
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Arrange the compounds of each set in order of reactivity towards $S_N2$ displacement: $1-$Bromobutane, $1-$Bromo$-2,2-$dimethylpropane, $1-$Bromo$-2-$methylbutane, $1-$Bromo$-3-$methylbutane.