MCQ
Which is most reactive of the following
- AEthyl acetate
- BAcetic anhydride
- CAcetamide
- ✓Acetyl chloride
$RCOCl > {(RCO)_2}O > RCOOR' > RCON{H_2}$
In other words, the reactivity decreases as the basicity of the leaving group increases i.e.,
$C{l^ - } < RCO{O^ - } < R{O^ - } < NH_2^ - $
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| column $(I)$ | column $(II)$ | ||
| $(A)$ | Kohlraush law | $(i)$ | $\Lambda _{eq}^o = \Lambda _c^o + \Lambda _a^o$ |
| $(B)$ | Molar Conductivity |
$(ii)$ | $\Lambda _m = \frac{{K \times 1000}}{M}$ |
| $(C)$ | Degree of Dissociation |
$(iii)$ | $\alpha = {\Lambda _m}/\Lambda _m^o$ |
| $(D)$ | Dissociation Constant |
$(iv)$ | ${k_a} = C{\alpha ^2}/1 - \alpha $ |
