- A$\Delta H = \Delta E + \,P\,\Delta V$
- B$\Delta H\, = \,\Delta E\, + \,n\,RT$
- ✓$\Delta H = \Delta E\, - \,P\,\Delta V$
- D$\Delta E = \Delta H\, - \,P\,\Delta V$
$\Rightarrow \Delta E=\Delta H-P \Delta V \rightarrow$ (d)
Also $\Delta H=\Delta E+\Delta n_gRT$ or
$=\Delta E+n RT \rightarrow(b)$
$\Delta H=\Delta E-P \Delta V$ is bonding relation
Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.
Assertion $A$ : Boric acid is a weak acid
Reason $R$ : Boric acid is not able to release $H ^{+}$ion on its own. It receives $OH ^{-}$ion from water and releases $H ^{+}$ion.
In the light of the above statements, choose the most appropriate answer from the options given below.
Step $I\,\,:$ ${H_2}O(g)\, \to \,H(g)\, + \,OH(g)\,;$ $\Delta H = 498\,kJ\,mol^{-1}$
Step $II\,\,:$ $OH(g)\, \to \,H(g)\, + \,O(g)\,;$ $\Delta H = 428\,kJ\,mol^{-1}$
The bond enthalpy of the $O-H$ bond is....$kJ\,mol^{-1}$
[Atomic mass : $\mathrm{H}: 1.0, \mathrm{C}: 12.0, \mathrm{O}: 16.0]$
| $Bond$ | $E_{(diss)}(kJ(mol )^{(-1)})$ |
| $C-A$ | $240$ |
| $C-B$ | $328$ |
| $C-C$ | $276$ |
| $C-D$ | $485$ |