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$BrO_{3(aq)}^ - \, + \,5Br_{(aq)}^ - \, + \,6{H^ - }\, \to \,3B{r_{2(l)}}\, + \,3{H_2}{o_{(l)}}.$
The rate of appearance of bromine $(Br_2)$ is related to rate of disappearance of bromide ions as
This reaction was studied at $-10^{\circ} C$ and the following data was obtained
| run | $[ NO ]_{0}$ | $\left[ Cl _{2}\right]_{0}$ | $r _{0}$ |
| $1$ | $0.10$ | $0.10$ | $0.18$ |
| $2$ | $0.10$ | $0.20$ | $0.35$ |
| $3$ | $0.20$ | $0.20$ | $1.40$ |
$[ NO ]_{0}$ and $\left[ Cl _{2}\right]_{0}$ are the initial concentrations and $r _{0}$ is the initial reaction rate.
The overall order of the reaction is ..........
(Round off to the Nearest Integer).
$2 A + B \longrightarrow C + D$
| Experiment | $[ A ] / molL ^{-1}$ | $[ B ] / molL ^{-1}$ | Initial $rate/molL$ $^{-1}$ $\min ^{-1}$ |
| $I$ | $0.1$ | $0.1$ | $6.00 \times 10^{-3}$ |
| $II$ | $0.1$ | $0.2$ | $2.40 \times 10^{-2}$ |
| $III$ | $0.2$ | $0.1$ | $1.20 \times 10^{-2}$ |
| $IV$ | $X$ | $0.2$ | $7.20 \times 10^{-2}$ |
| $V$ | $0.3$ | $Y$ | $2.88 \times 10^{-1}$ |
$X$ and $Y$ in the given table are respectively :
