4. d and f- block elements — Chemistry STD 12 Science — Question

${C_6}{H_5}CHO + C{H_3} - CHO\xrightarrow{{\mathop O\limits^\Theta  H}}$ Product

will be

$\mathrm{CH}_{3} \mathrm{COOH}+\mathrm{SOCl}_{2} \longrightarrow \mathrm{A} \xrightarrow[AlCl_3]{Benzene} \mathrm{B} \xrightarrow[-OH]{KCN} \mathrm{C}$

$Z{n^{2 + }}\,(aq)\, + \,2e\, \rightleftharpoons \,Zn\,(s)\,;\, - \,0.762\,V$

$C{r^{3 + }}\,(aq)\, + \,3e\, \rightleftharpoons \,Cr(s)\,;\, - \,0.740\,\,V$

$2{H^ + }\,(aq)\, + \,2e\, \rightleftharpoons \,{H_2}(g)\,;\,\,\,0.00\,\,\,V$

$F{e^{3 + }}\,(aq)\, + \,e\, \rightleftharpoons \,F{e^{2 + }}(aq)\,;\,\,\,0.770\,\,\,V$

Which is the strongest reducing agent ?

$2NO_2(g) + O_3(g) \to N_2O_5(g) + O_2(g)$

rate law is $R = K\, [NO_2]' [O_3]'$.

Which of these possible reaction mechanisms is consistent with the rate law?

Mechanism $I :$

$NO_2(g) + O_3(g) \to NO_3(g) + O_2(g)$ (slow)

$NO_3(g) + NO_2(g) \to N_2O_5(g)$ (fast)

Mechanism $II :$

$O_3(g)  \rightleftharpoons  O_2(g) + [O]$ (fast)

$NO_2(g) + [O] \to NO_3$ (slow)

$NO_3(g) + NO_2(g) \to  N_2O_5$ (fast)