- AF, Cl, Br, I
- BI, Br, Cl, F
- CBr, Cl, F, I
- DCl, Br, I, F
Explanation:
The bond between carbon and the halogen atom (C-X) is polar. Since halogen atoms are more electronegative than carbon, there is partial negative charge on halogen atom and positive charge on carbon.
This makes the molecule dipolar and polar nature of C-X bond is increase with increase in the electronegativity difference between carbon and halogen atom.
Hence the order of polarity of C−X bond is C−F>C−Cl>C−Br>>C−I.
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Statement $I$: The boiling point of hydrides of Group $16$ elements follow the order
$\mathrm{H}_2 \mathrm{O}>\mathrm{H}_2 \mathrm{Te}>\mathrm{H}_2 \mathrm{Se}>\mathrm{H}_2 \mathrm{~S}$.
Statement $II$: On the basis of molecular mass, $\mathrm{H}_2 \mathrm{O}$ is expected to have lower boiling point than the othe members of the group but due to the presence of extensive $\mathrm{H}$-bonding in $\mathrm{H}_2 \mathrm{O}$, it has higher boiling point.
In the light of the above statements, choose the correct answer from the options given below: