- ✓$HCOOH\,(3.77)$
- B${C_6}{H_5}COOH\,(4.22)$
- C$C{H_3}COOH\,(4.71)$
- D$C{H_3}C{H_2}COOH\,(4.88)$
: Formic acid with lower $\mathrm{pK}_{\mathrm{a}}$ value of 3.77 is the strongest acid.
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$CH _{3} COOH + NaOH \rightarrow CH _{3} COONa + H _{2} O$ $(\Delta H =-55.3\,kJ\,mol ^{-1})$ The enthalpy of ionization of $CH _{3} COOH$ as calculated by the student is $kJ mol ^{-1}$. (nearest integer)

$(i)\,\begin{array}{*{20}{c}}
{C{H_3} - \mathop C\limits^ \oplus - C{H_3}} \\
| \\
{\,\,\,\,\,\,OC{H_3}}
\end{array}$
$(ii)\,\begin{array}{*{20}{c}}
{C{H_3} - \mathop C\limits^ \oplus - C{H_3}} \\
| \\
{\,\,\,\,\,\,C{H_3}}
\end{array}$
$(iii)\begin{array}{*{20}{c}}
{C{H_3} - \mathop C\limits^ \oplus {H_2} - NH} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}$
$(iv)\,C{H_3} - \mathop C\limits^ \oplus {H_2}$