MCQ
Which is the strongest acid ? ($pKa$ value is given in the bracket)
- ✓$HCOOH\,(3.77)$
- B${C_6}{H_5}COOH\,(4.22)$
- C$C{H_3}COOH\,(4.71)$
- D$C{H_3}C{H_2}COOH\,(4.88)$
: Formic acid with lower $\mathrm{pK}_{\mathrm{a}}$ value of 3.77 is the strongest acid.
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(Given ${\Delta _{fus}}H = 6\, kJ\, mol^{-1}$ at $0\,^oC$,
$C_p(H_2O, l) =75.3\, J\, mol^{-1} \, K^{-1}$ ,
$C_p(H_2O, s) = 36.8\, J\, mol^{-1} \, K^{ -1}$ )
In which case the value of $\Delta H_{sol.} < 0$