MCQ
Which metal sulphide is soluble in excess $NH_3$ solution ?
- A$ZnS$
- B$MnS$
- C$FeS$
- ✓$Cr_2S_3$
$C{r_2}{S_3} + 6N{H_3}\, \rightleftharpoons \,{[Cr{(N{H_3})_6}]^{3 + }}\, + \,{S^{2 - }}(aq.)$
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| Column $I$ | Column $II$ |
| $(A) \,XX '$ | $(i)$ $T-$shape |
| $(B)\,XX'_3$ | $(ii)$ Pentagonal bipyramidal |
| $(C)\,XX '_5$ | $(iii)$ Linear |
| $(D)\,XX '_7$ | $(iv)$ Square pyramidal |
| $(v)$ Tetrahedral |
| $LIST-I$ | $LIST-II$ |
| $(I)$ Aniline | $(P)$ Sodium fusion extract of the compound on boiling with $FeSO _4$, followed by acidification with conc. $H _2 SO _4$, gives Prussian blue color. |
| $(II)$ o-Cresol | $(Q)$ Sodium fusion extract of the compound on treatment with sodium nitroprusside gives blood red color. |
| $(III)$ Cysteine | $(R)$ Addition of the compound to a saturated solution of $NaHCO _3$ results in effervescence. |
| $(IV)$ Coprolactam | $(S)$ The compound reacts with bromine water to give a white precipitate. |
| $(T)$ Treating the compound with neutral $FeCl _3$ solution produces violet color. |