Which of following will not gives primary amine with $LiAlH_4$
A$\begin{array}{*{20}{c}}
O\\
{||}\\
{C{H_3} - C - N{H_2}}
\end{array}$
B
C$C{H_3} - C \equiv N$
D$CH_3 -NO_2$
Difficult
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B
b
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An organic compound $(C_3H_9N)\,\, (A),$ when treated with nitrous acid, gave an alcohol and $N_2$ gas was evolved. $(A)$ on warming with $CHCl_3$ and caustic potash gave $(C)$ which on reduction gave isopropylmethylamine. Predict the structure of $(A).$
Cyclohexylamine when treated with nitrous acid yields $(P)$. On treating $(P)$ with $P C C$ results in $(Q)$. When $(Q)$ is heated with dil. $NaOH$ we get $(R)$ The final product $(R)$ is :