MCQ
Which of the following aqueous solution will exhibit highest boiling point
- A$0.01\, M$ $Na_2SO_4$
- B$0.01\, M$ $KNO_3$
- ✓$0.015\, M$ urea
- D$0.015\, M$ glucose
$\Longrightarrow 3.72=1 \times 1.86 \times i$
$\Longrightarrow i=2,$ hence complex is binary.
Also, $C N$ of $P t$ is $6$ and complex is hydrated.
so complex is $\left[ Pt \left( H _{2} O \right)_{3} Cl _{3}\right] Cl \cdot 3 H _{2} O$
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$CHCl_3\xrightarrow[hv]{O_2}[A]\xrightarrow{EtOH}[B]\xrightarrow{2\ mole\ MeMgBr}$
$[C]\xrightarrow{CaOCl_2}[D]\xrightarrow{\Delta}CH_3-\underset{\underset{O}{||}}{C}-CH_3$
$(A)$ $\left. Na _{4}\left[ Fe ( CN )_{5} NOS \right)\right]$
$(B)$ $Na _{4}\left[ FeO _{4}\right]$
$(C)$ $\left[ Fe _{2}( CO )_{9}\right]$

(Use $\mathrm{R}=0.083 \mathrm{~L}$ bar mol $\mathrm{m}^{-1} \mathrm{~K}^{-1}$ )