MCQ
Which of the following are isoelectronic and isostructural?

                                    $NO^-_3, CO^{2-}_3 ,CO^-_3 ,SO_3$

  • A
    $NO_3^- , CO^{2-}_3$ 
  • B
    $SO_3 , NO_3^-$
  • C
    $ClO_3^- , CO^{2-}_3$
  • D
    $CO^{2-}_3, ClO_3^-$

Answer

Number of electrons in the compound is:

$\mathrm{NO}_{3}^{-}=32 \mathrm{e}^{-}$

$\begin{array}{l}\mathrm{CO}_{3}^{2-}=32 \mathrm{e}^{-} \\\mathrm{ClO}_{3}^{-}=42\mathrm{e}^{-}\end{array}$

$\mathrm{SO}_{3}^{-}=41 \mathrm{e}^{-}$

Therefore, $\mathrm{NO}_{3}^{-}$ and $\mathrm{CO}_{3}^{2-}$ are isoelectronic The structures of both $\mathrm{NO}_{3}^{-}$ and $\mathrm{CO}_{3}^{2-}$ is trigonal planar. Therefore $\mathrm{NO}_{3}^{-}$ and $\mathrm{CO}_{3}^{2-}$ are isostructural also.

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free