MCQ
Which of the following complexes is strongest reducing agent
- ✓$[Co(CN)_6]^{-4}$
- B$[Co(CN)_6]^{-3}$
- C$[Ag(CN)_2]^{-1}$
- D$[Co(CN)_4]^{-3}$
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Intermediates of the reaction is/are
If the rate of formation of $B$ is set to be zero then the concentration of $B$ is given by :
| Observation | $[A]$ | $[B]$ | Rate of reaction |
| $1$ | $0.1$ | $0.1$ | $2\times10^{-3}\, mol\, L^{-1}\,sec^{-1}$ |
| $2$ | $0.2$ | $0.1$ | $0.4\times10^{-2}\, mol\, L^{-1}\,sec^{-1}$ |
| $3$ | $0.1$ | $0.2$ | $1.4\times10^{-2}\, mol\, L^{-1}\,sec^{-1}$ |
Assertion ($A$): Enthalpy of neutralisation of strong monobasic acid with strong monoacidic base is always $-57 \mathrm{~kJ} \mathrm{~mol}^{-1}$
Reason ($R$): Enthalpy of neutralisation is the amount of heat liberated when one mole of $\mathrm{H}^{+}$ions furnished by acid combine with one mole of ${ }^{-} \mathrm{OH}$ ions furnished by base to form one mole of water. In the light of the above statements, choose the correct answer from the options given below.
