MCQ
Which of the following compound is diamagnetic
  • A
    $K_4[Fe^{+2}(CN)_5(O_2 )]$
  • $[NiF_6]^{-2}$
  • C
    $[Fe(H_2O)_5(NO)]^{+2}$
  • D
    All of these

Answer

Correct option: B.
$[NiF_6]^{-2}$
b
$K_4[Fe^{+2}(CN)_5(O_2)]$ is paramagnetic due to $O_2^\circleddash$

$[NiF_6]^{2-} \to d^2sp^3$ hybridisation, diamagnetic

$[Fe(H_2O)_5(NO)]^{+2} \to $ paramagnetic

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