MCQ
Which of the following has the highest molar conductivity?
- ✓$[Co(NH_3)_6]Cl_3$
- B$[Co(NH_3)_5Cl]Cl_2$
- C$[Co(NH_3)_4Cl_2]Cl_2$
- D$[Co(NH_3)_3Cl_3]$
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$\underset{{{C}_{3}}{{H}_{6}}C{{l}_{2}}}{\mathop{A}}\,\,\xrightarrow[2.\,\,{{H}^{+}}\,\,(\min d)]{\begin{smallmatrix}
1\,.\,\,alcoholic\,\,KOH\,/\,\Delta \\
followed\,\,by\,\,NaN{{H}_{2}}\,/\,\Delta
\end{smallmatrix}}$ $B\,\xrightarrow[{{H}_{2}}{{O}_{2}}/\overset{\Theta }{\mathop{O}}\,H]{{{B}_{2}}{{H}_{6}}}C$
$A\,\xrightarrow{aq.\,\,KOH\,(excess)}C$
Assertion $(A)$ : Vinyl halides do not undergo nucleophilic substitution easily.
Reason $(R)$ : Even though the intermediate carbocation is stabilized by loosely held $p-$ electrons, the cleavage is difficult because of strong bonding.