STD 11 - 3. Classification of elements and periodicity in properties — NEET STD 11 Science — Question

$xMnO_4^ - \, + \,y{C_2}O_4^{2 - }\, + \,z{H^ + }\, \rightarrow $$\,xM{n^{2 + }} + 2yC{O_2} + \frac{z}{2}{H_2}O$

The value's of $x, y$ and $z$ in the reaction are, respectively :

$\begin{array}{*{20}{c}}
  {C{H_2} - CH - C{H_2}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,OH\,\,\,\,\,\,OH} 
\end{array}$

is :

$\Delta_{f} \mathrm{H}^{\ominus}$ for $\mathrm{KCl}=-436.7 \,\mathrm{~kJ}\, \mathrm{~mol}^{-1}$

$\Delta_{\text {sub }} \mathrm{H}^{\ominus}$ for $\mathrm{K}=89.2 \,\mathrm{~kJ}\, \mathrm{~mol}^{-1}$

$\Delta_{\text {ionization }} \,\mathrm{H}^{-}$ for $\mathrm{K}=419.0\, \mathrm{~kJ}\, \mathrm{~mol}^{-1}$

$\Delta_{\text {electron gain }} \mathrm{H}^{\ominus}$ for $\mathrm{Cl}_{(\text {e) }}=-348.6 \,\mathrm{~kJ} \,\mathrm{~mol}^{-1}$

$\Delta_{\mathrm{bond}} \mathrm{H}^{-}$ for $\mathrm{Cl}_{2}=243.0 \,\mathrm{~kJ} \,\mathrm{~mol}^{-1}$

The magnitude of lattice enthalpy of $\mathrm{KCl}$ in $\mathrm{kJ} \mathrm{mol}^{-1}$ is ..... . (Nearest integer)

$\begin{array}{*{20}{c}} {{H_3}C - C{H_2} - CH - Et} \\ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \end{array}$ about $C_2-C_3$ is (figure)