- AWater + ethanol
- BChloroform + carbon tetrachloride
- ✓Benzene + toluene
- DWater + hydrochloric acid
Chloroform $+$ carbon tetrachloride show positive deviation from Raoult's law Water $+ HCl$ is a non-ideal solution showing negative deviations from Raoult's law.
In a Benzene-toluene mixture, $A - B$ interactions are almost equal to $A - A$ and $B -B$ interactions due to the very small difference in the two compounds, i.e., they differ just by one $CH_2$ group. Hence, no deviation will occur from Raoult's law.
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$(i)$ ter. butyl chloride easily hydrolysed to gives alcohol
$(ii$) sec. alcohol gives blue colour in victer-meyer test
$(iii)$ $IUPAC$ name of (figure) is $3-$ methylpentan $-2-$ ol
$(iv)$ alcohol release $H_2$ gas with Grignard reagent
| Observation | $[A]$ | $[B]$ | Rate of reaction |
| $1$ | $0.1$ | $0.1$ | $2\times10^{-3}\, mol\, L^{-1}\,sec^{-1}$ |
| $2$ | $0.2$ | $0.1$ | $0.4\times10^{-2}\, mol\, L^{-1}\,sec^{-1}$ |
| $3$ | $0.1$ | $0.2$ | $1.4\times10^{-2}\, mol\, L^{-1}\,sec^{-1}$ |