MCQ
Which of the following is correct ?
  • The members of $B_nH_{n+6}$ are less stable than $B_nH_{n+4}$ series
  • B
    Diborane is coloured and unstable at room temperature
  • C
    The reaction of diborane with oxygen is endothermic
  • D
    All of the above

Answer

Correct option: A.
The members of $B_nH_{n+6}$ are less stable than $B_nH_{n+4}$ series
a
The members of $B _{ n } H _{ n +6}$ are less stable than $B _{ n } H _{ n +4}$ series.

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$\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{Br}+\mathrm{Z}^{-}$$\xrightarrow[{{\text{Sublimation}}}]{{{k_s}}} \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{Z}+\mathrm{Br}^{-}$

$\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{Br}+\mathrm{Z}^{-}$$\xrightarrow[{{\text{elimination}}}]{{{k_e}}}\mathrm{CH}_{3} \mathrm{CH}= \mathrm{CH}_{2} +\mathrm{HZ}+\mathrm{Br}^{-}$

where 

$\mathrm{Z}^{-}=\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{O}^{-}(\mathrm{A})$ or $\begin{array}{*{20}{c}}
  {\,C{H_3}} \\ 
  {|\,\,\,\,\,} \\ 
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  {|\,\,\,\,} \\ 
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\end{array}$

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  {C{H_3} - CH - C{H_2} - C{H_3}\xrightarrow[{hv}]{{C{l_2}}}} \\ 
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