- A$N{O^ + }$
- B$CO$
- C$O_2^{2 - }$
- ✓$B_2$
$NO^+$ $14$
$CO$ $14$
$O_2^{2-}$ $18$
$B_2$ $10$
$N{O^ + } \Rightarrow KK.\sigma {(2s)^2}{\sigma ^*}{(2s)^2}.{(\pi 2{p_x})^2}$
$ = {(\pi 2{p_y})^2}.{(\sigma 2{p_z})^2}$ diamagnetic
$CO \Rightarrow KK.\sigma {(2s)^2}{\sigma ^*}{(2s)^2}.{(\pi 2{p_x})^2}$
$ = {(\pi 2{p_y})^2}.{(\sigma 2{p_z})^2}$ diamagnetic
$O_2^{2 - } \Rightarrow KK.\sigma {(2s)^2}{\sigma ^*}{(2s)^2}.\sigma {(2{p_z})^2}{(\pi 2{p_x})^2}$
$ = {(\pi 2{p_y})^2}.{\pi ^*}{(2{p_x})^2} = {\pi ^*}{(2{p_y})^2}$ diamagnetic
${B_2} \Rightarrow KK.\sigma {(2s)^2}{\sigma ^*}{(2s)^2}.\pi {(2{p_x})^1} = \pi {(2{p_y})^1}$ paramagnetic
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This reaction was studied at $-10^{\circ} C$ and the following data was obtained
| run | $[ NO ]_{0}$ | $\left[ Cl _{2}\right]_{0}$ | $r _{0}$ |
| $1$ | $0.10$ | $0.10$ | $0.18$ |
| $2$ | $0.10$ | $0.20$ | $0.35$ |
| $3$ | $0.20$ | $0.20$ | $1.40$ |
$[ NO ]_{0}$ and $\left[ Cl _{2}\right]_{0}$ are the initial concentrations and $r _{0}$ is the initial reaction rate.
The overall order of the reaction is ..........
(Round off to the Nearest Integer).
[Given : $pKa$ (acetic acid) $=4.74$ ]

