MCQ
Which of the following is Sanger reagent ?
- ✓$2,4$ -Di- nitro flurobenzene
- BPhenyl isocyanate
- C$2, 4$ -Di- nitro chlorobenzene
- D$2, 4$ -Di- nitro iodoberizene
Sanger's reagent: A) $2,4-Dinitroflurobenzene$ structure:
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$F_{2(g)} + 2e^- \rightarrow 2F^-_{(aq)}\, ;$ $E^o = + 2.85\, V$
$Cl_{2(g)} + 2e^- \rightarrow 2Cl^-_{(aq)}\, ;$ $E^o = + 1.36\, V$
$Br_{2(l)} + 2e^- \rightarrow 2Br^-_{(aq)}\, ;$ $E^o = + 1.06\, V$
$I_{2(s)} + 2e^- \rightarrow 2I^-_{(aq)}\, ;$ $E^o = + 0.53\, V$
The strongest oxidising and reducing agents respectively are
| Column $-I$ | Column $-II$ |
| (Atomic number) | (Position of element in Periodic table) |
| $(A)$ $Z = 37$ | $(P)$ $p-$ block |
| $(B)$ $Z = 42$ | $(Q)$ $f-$ block |
| $(C)$ $Z = 34$ | $(R)$ $d-$ block |
| $(D)$ $Z = 92$ | $(S)$ $s-$ block |