MCQ
Which of the following pairs of molecules is isoelectronic as-well as iso structrural
  • $NO_3^ - ,CO_3^{ - 2}$
  • B
    $S{O_3},N{O_3}$
  • C
    $ClO_3^ - ,CO_3^{ - 2}$
  • D
    $CO_3^{ - 2},S{O_3}$

Answer

Correct option: A.
$NO_3^ - ,CO_3^{ - 2}$
a
Number of electrons in the compound is:

$NO _3^{-}=32 e ^{-}$

$CO _3^{2-}=32 e ^{-}$

$ClO _3^{-}=42 e ^{-}$

$SO _3^{-}=41 e ^{-}$

Therefore, $NO _3^{-}$and $CO _3^{2-}$ are isoelectronic

The structures of both $NO _3^{-}$and $CO _3^{2-}$ is trigonal planar.

Therefore $NO _3^{-}$and $CO _3^{2-}$ are isostructural also.

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