MCQ
Which of the following pairs represent linkage isomers?
  • $[Pd(P\, PH_3)_2(NCS)_2]$ and $[Pd \,( P \,PH_3)_2\, (SCN)_2]$
  • B
    $[Co(NH_3)_5NO_3] SO_4$ and $[Co(NH_3)_5SO_4]NO_3$
  • C
    $[PtCl_2( NH_3)_4 ] Br_2$ and $[Pt Br_2 (NH_3 )_4 ] Cl_2$
  • D
    $[Cu(NH_3)_4][Pt Cl_4]$ and $[Pt(NH_3)_4][CuCl_4]$

Answer

Correct option: A.
$[Pd(P\, PH_3)_2(NCS)_2]$ and $[Pd \,( P \,PH_3)_2\, (SCN)_2]$
a
The $S C N^{-}$ ion can coordinate through $S$ or $N$ atom giving rise to linkage isomerism

$M \leftarrow S C N$ thiocyanto

$M \leftarrow N C S$ isothiocyanato.

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

Which of the following order regarding stability of phosphorous is correct ?
Nitrogen detection in an organic compound is carried out by Lassaigne's test. The blue colour formed corresponds to which of the following formulae ?
Arrange acidity of given four compounds in decreasing order :

$(I)$  $\begin{array}{*{20}{c}}
  {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {C{H_3} - C - C{H_2} - C - C{H_3}} 
\end{array}$

$(II)$ $\begin{array}{*{20}{c}}
  O \\ 
  {||} \\ 
  {C{H_3} - C - C{H_3}} 
\end{array}$

$(III)$ $CH \equiv CH$

$(IV)$ $CH_3-CHO$

Select correct answer from the codes given below :

Codes : 

Ethanol when reacted with $PCl_5$ gives $A$, $POCl_3$ and $HCl$. $A$ reacts with silver nitrite to form $B$ (major product) and $AgCl$. $A$ and $B$ respectively are
The two forms of $D-$ glucopyranose obtained from the solution of $D-$ glucose are called
In the reaction of hypobromite with amide, the carbonyl carbon is lost as :
Among the following, the number of halide$(s)$ which is/are inert to hydrolysis is ..........

$(A)$ $BF _{3}$

$(B)$ $SiCl _{4}$

$(C)$ $PCl _{5}$

$(D)$ $SF _{6}$

When acidified $K_2Cr_2O_7$ react with $H_2O_2$ a blue colour solution is obtained. This blue colour is due to the formation of
At $25^{\circ} C$, the molar conductance at infinite dilution for the strong electrolytes $NaOH ,$ $NaCl$ and $BaCl _{2}$ are $248 \times 10^{-4}, 126 \times 10^{-4}$ and $280 \times 10^{-4} \,Sm ^{2} mol ^{-1}$ respectively. $\lambda_{m}^{o} B a(O H)_{2}$ in $S m^{2} m o l^{-1}$ is

 

Which of the following kinds of isomerism can nitroethane exhibit ?