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Assertion $(A)$ : $\mathrm{S}_{\mathrm{N}} 2$ reaction of $\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{Br}$ occurs more readily than the $\mathrm{S}_{\mathrm{N}} 2$ reaction of $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{Br}$.
Reason $(R)$ : The partially bonded unhybridized p-orbital that develops in the trigonal bipyramidal transition state is stabilized by conjugation with the phenyl ring.
In the light of the above statements, choose the most appropriate answer from the options given below:
$\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|| \\
HOC{{H}_{2}}C{{H}_{2}}CHC{{H}_{2}}C{{H}_{2}}COH \\
\end{matrix}$ $\xrightarrow[tetrahydro\,\,futan ]{(x)\,\,C{{H}_{3}}Li}$ $\xrightarrow[{{H}_{2}}]{N{{H}_{4}}Cl}$ $\underset{Compound\,\,\,A\,\,63\,\%}{\mathop{\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O\, \\
\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|| \\
HOC{{H}_{2}}C{{H}_{2}}CHC{{H}_{2}}C{{H}_{2}}-C-C{{H}_{3}} \\
\end{matrix}}}\,$ $\underset{37\,\%}{\mathop{+\,\,Compound\,\,(B)}}\,$
Value of $(x)$ in above reaction is
In the above first order reaction the initial concentration of $\mathrm{N}_{2} \mathrm{O}_{5}$ is $2.40 \times 10^{-2}\, \mathrm{~mol} \,\mathrm{~L}^{-1}$ at $318 \,K.$ The concentration of $\mathrm{N}_{2} \mathrm{O}_{5}$ after $1\, hour$ was $1.60 \times 10^{-2}\, \mathrm{~mol} \,\mathrm{~L}^{-1}$, The rate constant of the reaction at $318\, \mathrm{~K}$ is $.....\,\times 10^{-3} \mathrm{~min}^{-1}$. (Nearest integer)
[Given: $\log 3=0.477, \log 5=0.699$ ]
(image) $+ NaNO_2+HCl \rightarrow $ product