MCQ
Which of the following statements is wrong?
  • A
    Ethyl chloride on reduction with $Zn-Cu$ couple and alcohol gives ethane.
  • The reaction of methyl magnesium bromide with acetone gives butanol $-2$
  • C
    Alkyl halides follow the following reactivity sequence on reaction with alkenes.
    $R - I > R - Br > R - Cl > R - I$
  • D
    $C_2H_4Cl_2$ may exist in two isomeric forms

Answer

Correct option: B.
The reaction of methyl magnesium bromide with acetone gives butanol $-2$
b
$\begin{matrix}
   C{{H}_{3}}  \\
   C{{H}_{3}}  \\
\end{matrix}>\,C\,=\,O\,+\,C{{H}_{3}}C{{H}_{2}}MgBr\,\to $  $\begin{matrix}
   C{{H}_{3}}  \\
   C{{H}_{3}}  \\
\end{matrix}>\,C\,<\,\begin{matrix}
   OMgBr  \\
   C{{H}_{2}}C{{H}_{3}}  \\
\end{matrix}\,\xrightarrow{{{H}_{2}}O}$  $\underset{\begin{smallmatrix} 
 2\,\,methyl\,\,bu\tan ol\,\,-\,2 \\ 
 \,\,\,\,\,\,\,({{3}^{o}}\,\,alcohol) 
\end{smallmatrix}}{\mathop{\begin{matrix}
   C{{H}_{3}}  \\
   C{{H}_{3}}  \\
\end{matrix}>\,C\,<\,\begin{matrix}
   OH  \\
   C{{H}_{2}}C{{H}_{3}}  \\
\end{matrix}}}\,$

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