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What is $Y$ in the above reaction?
$3 \mathrm{PbCl}_2+2\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4 \rightarrow \mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2+6 \mathrm{NH}_4 \mathrm{Cl}$
If $72 \mathrm{mmol}$ of $\mathrm{PbCl}_2$ is mixed with $50 \mathrm{mmol}$ of$\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4$, then amount of $\mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2$ formed is......... mmol. (nearest integer)
$\mathrm{M}(\mathrm{s}) \mid \mathrm{M}^{+}$(aq; $0.05$ molar) || $\mathrm{M}^{+}(\mathrm{aq}), 1$ molar) $\mid \mathrm{M}(\mathrm{s})$
For the above electrolytic cell the magnitude of the cell potential $\left|E_{\text {cell }}\right|=70 \mathrm{mV}$.
$1.$ For the above cell
$(A)$ $\mathrm{E}_{\text {cell }}<0 ; \Delta \mathrm{G}>0$ $(B)$ $\mathrm{E}_{\text {cell }}>0 ; \Delta \mathrm{G}<0$
$(C)$ $\mathrm{E}_{\text {cell }}<0 ; \Delta \mathrm{G}^{\circ}>0$ $(D)$ $\mathrm{E}_{\text {cell }}>0 ; \Delta \mathrm{G}^{\circ}>0$
$2.$ If the $0.05$ molar solution of $\mathrm{M}^{+}$is replaced by $0.0025$ molar $\mathrm{M}^{+}$solution, then the magnitude of the cell potential would be
$(A)$ $35 \mathrm{mV}$ $(B)$ $70 \mathrm{mV}$ $(C)$ $140 \mathrm{mV}$ $(D)$ $700 \mathrm{mV}$
Give the answer question $1,2.$