- ATransition elements.
- Bs-block elements.
- Cf-block elements.
- DBoth (a) and (c).
Explanation:
Variable valency is exhibited by transition elements and f-block elements.
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$HSO_4^- = 1.2 \times 10^{- 2} ,H_2PO_4^- = 6.3 \times 10^{-8} ,$$HCO_3^- = 4.7 \times 10^{-11}$
$\left[\mathrm{PtCl}_{4}\right]^{2-}+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons\left[\mathrm{Pt}\left(\mathrm{H}_{2} \mathrm{O}\right) \mathrm{Cl}_{3}\right]^{-}+\mathrm{Cl}^{-}$
was measured as a function of concentrations of different species. It was observed that
$\frac{-\mathrm{d}\left[\left[\mathrm{PtCl}_{4}\right]^{2-}\right]}{\mathrm{dt}}=4.8 \times 10^{-5}\left[\left[\mathrm{PtCl}_{4}\right]^{2-}\right]-2.4 \times10^{-3}\left[\left[\mathrm{Pt}\left(\mathrm{H}_{2} \mathrm{O}\right) \mathrm{Cl}_{3}\right]^{-}\right]\left[\mathrm{Cl}^{-}\right]$
where square brackets are used to denote molar concentrations. The equilibrium constant $\mathrm{K}_{\mathrm{c}}=....$. (Nearest integer)

$(R = 0.083\, L\, bar\, K^{-1} \,mol^{-1})$