MCQ
Which of the following will show optical activity ?
- ✓$A, D$ and $ E$
- B$A$ and $E$ only
- C$B, C$ and $D$
- DAll except $C$
$(2)\, 50/50$ mixture of diastereoisomers is also optically active.
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$PhC{{O}_{2}}H\xrightarrow[2.\,N{{H}_{3}}]{1.\,PC{{l}_{5}}}A\xrightarrow[2.\,{{H}_{2}}/Ni]{1.\,{{P}_{4}}{{O}_{10}}.heat}B.$ The final product $(B)$ is
$2 \mathrm{NO}_{(\mathrm{g})}+2 \mathrm{H}_{2(\mathrm{~g})} \rightarrow \mathrm{N}_{2(\mathrm{~g})}+2 \mathrm{H}_{2} \mathrm{O}_{(\mathrm{g})}$
|
$[NO]$ $\mathrm{mol} \mathrm{L}^{-1}$ |
${H}_{2}$ $\mathrm{mol} \mathrm{L}^{-1}$ |
Rate $\mathrm{mol}L^{-1}$ $s^{-1}$ |
|
| $(A)$ | $8 \times 10^{-5}$ | $8 \times 10^{-5}$ | $7 \times 10^{-9}$ |
| $(B)$ | $24 \times 10^{-5}$ | $8 \times 10^{-5}$ | $2.1 \times 10^{-8}$ |
| $(C)$ | $24 \times 10^{-5}$ | $32 \times 10^{-5}$ | $8.4 \times 10^{-8}$ |
The order of the reaction with respect to $\mathrm{NO}$ is ..... .