- A$C{O_2}$
- B${N_2}O$
- ✓$S{O_2}$
- D$CO$
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$\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2} - C{H_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{C{H_3} - CH - CH - C{H_2} - CH - C{H_3}} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_2} - C{H_{3\,\,\,\,}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
In the above first order reaction the concentration of $\mathrm{PCl}_{5}$ reduces from initial concentration $50\, mol\,\mathrm{L}^{-1}$ to $10\, \mathrm{~mol} \,\mathrm{~L}^{-1}$ in $120\, minutes$ at $300\, \mathrm{~K}$. The rate constant for the reaction at $300\, \mathrm{~K}$ is $\mathrm{X}$ $\times 10^{-2} \mathrm{~min}^{-1}$. The value of $x$ is $......$
$[$ Given $\log 5=0.6989]$