Question
Which one of the following is a primary standard?

Answer

The primary standard is a compound of sufficient purity from which standard solutions of known normalities can be prepared by direct weighing of it and diluting to a defined volume of solution.
Potassium Dichromate $\ce{(K_2Cr_2O_7​)}$ is suitable to be used as a primary standard. It cannot be obtained in very pure form. It readily reacts with any traces of organic material or any other reducing substance in wate

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