- AResorcinol
- ✓Dimethyl glyoxime $ [DMG]$
- CDiphenyl benzidine
- DPotassium ferrocyanide

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Assertion $A$ : Aryl halides cannot be prepared by replacement of hydroxyl group of phenol by halogen atom.
Reason $R$ : Phenols react with halogen acids violently. In the light of the above statements, choose the most appropriate from the options given below:
$(1)$ An electron in an orbital of high angular momentum stays away from the nucleus than an electron in the orbital of lower angular momentum.
$(2)$ For a given value of the principal quantum number, the size of the orbit is inversely proportional to the azimuthal quantum number
$(3)$ According to wave mechanics, the ground state angular momentum is equal to $\frac {h}{2\pi }$
$(4)$ The plot of $\Psi \,\,Vs\,\,r$ for various azimuthal quantum numbers, shows peak shifting towards higher $r$ value
