MCQ
Which sequence represents the best synthesis of hexanal ?

$\underset{Hexanal}{\mathop{C{{H}_{3\text{ }}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}CH=O}}\,$

  • A
    $1$. $CH_3 CH_2CH_2 CH_2 Br + NaC =CH$

    $2$. $H_2O,H_2SO_4,HgSO_4$

  • B
    $\begin{matrix}
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O  \\
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||  \\
       1.\,\,C{{H}_{3\text{ }}}C{{H}_{2}}C{{H}_{2}}CH=C{{H}_{2}}+C{{H}_{3}}\,C\,OH  \\
    \end{matrix}$

    $2$. $CH_3 MgBr,$ diethyl ether

    $3$. $H_3O^+$

    $4$. $PCC, CH_2Cl_2$

  • C
    $\begin{matrix}
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O  \\
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||  \\
       1.\,\,C{{H}_{3\text{ }}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}\,C\,C{{H}_{3}}  \\
    \end{matrix}$

    $\begin{matrix}
       \,\,\,\,\,O  \\
       \,\,\,\,\,||  \\
       2.\,\,\,C{{H}_{3}}\,C\,OH  \\
    \end{matrix}$

    $3.\, LiAlH_4$

    $4.\, H_2O$

    $5.\, PCC, CH_2Cl_2$

  • $2.\, H_3O^{\oplus}$

    $3. \, PCC,CH_2Cl_2$

Answer

Correct option: D.
$2.\, H_3O^{\oplus}$

$3. \, PCC,CH_2Cl_2$

d

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