- ACH3CH2CH2CH2OCH3
- BCH3CH2OCH2CH3
- CCH3CH2CH2CH3
- DCH3CH2C=OCH3
Explanation:
CH3CH2CH2CH3 (n−butane) has the lowest boiling point as it has lowest molecular weight and is non polar. It has weakest intramolecular forces of attraction.
All others are polar compounds and so has dipole-dipole inbteraction.
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$\begin{array}{*{20}{c}}
{C{H_3} - CH - CH - C{H_3}\xleftarrow[{ether}]{{Na}}R\,' - Br\,\xrightarrow{{Mg}}'D'\,\xrightarrow{{{H_2}O}}E} \\
{\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{\,\,\,\,\,C{H_3}\,\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
$A$. Glycerol is purified by vacuum distillation because it decomposes at its normal boiling point.
$B$. Aniline can be purified by steam distillation as aniline is miscible in water.
$C$. Ethanol can be separated from ethanol water mixture by azeotropic distillation because it forms azeotrope.
$D$. An organic compound is pure, if mixed $M.P$. is remained same.
Choose the most appropriate answer from the options given below :