Question
Which will have enantiomer
$C{H_3}C{H_2} - \mathop {\mathop {\mathop {{C^ \bullet }}\limits_|^| }\limits^H - }\limits_{Cl\;} C{H_3}$
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$N{O_2} + {F_2}\xrightarrow{{slow}}N{O_2}F + F$
$N{O_2} + F\xrightarrow{{fast}}N{O_2}F$
Thus rate expression of the above reaction can be written as
$(i)$ $Zn|Zn^{2+}\,(1\,M)||Cu^{2+}\,(1\,M)|Cu$
$(ii)$ $Zn|Zn^{2+}\,(0.1\,M)||Cu^{2+}\,(1\,M)|Cu$
$(iii)$ $Zn|Zn^{2+}\,(1\,M)||Cu^{2+}\,(0.1\,M)|Cu$
$(iv)$ $Zn|Zn^{2+}(0.1\,M)||Cu^{2+}\,(0.1\,M)|Cu$
[Given $pK _{ a }$ of $CH _{3} COOH =4.57$ ]