MCQ
Why do the deviations occur from idealized shape of H2O and NH3 molecules?
- ASame hybridisation.
- BDifferent hybridisation.
- CRepulsive effect.
- DNone of these.
Explanation:
Greater repulsion between lone pairs of electrons as compared to the lone pair- bond pair and bond pair-bond pair repulsions. These repulsive effects result in deviations from idealised shapes and alterations in bond angles in the molecules.
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| Condition | Temperature |
| $(1)$ Spontaneous | $(p)$ $273\,K$ |
| $(2)$ At equilibrium | $(q)$ $260\, K$ |
| $(3)$ Non-spontaneous | $(r)$ $280\, K$ |
