Question
Why tetrahedral complexes do not exhibit geometrical isomerism.

Answer

In tetrahedral geometry
  1. All the four ligands are adjacent or equidistant to one another.
  2. The relative positions of donor atoms of ligands attached to the central metal atom are the same with respect to each other.
  3. It has a plane of symmetry. Therefore, tetrahedral complexes do not exhibit geometrical isomerism.

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