Question
Write a classification of aliphatic ketones with a suitable example.

Answer

On the basis of types of alkyl groups bonded to carbonyl carbon, aliphatic ketones are further classified as simple and mixed ketones.
Simple or symmetrical ketones: The ketones in which both the alkyl groups bonded to carbonyl carbon are identical are called simple ketones or symmetrical ketones.
e.g.

  • $\begin{array}{cc}
    \ce{O}\phantom{.......}\\
    ||\phantom{.......}\\
    \ce{\underset{\text{Dimethyl ketone (Acetone)}}{H3C - C - CH3}}
    \end{array}$
  • $\begin{array}{cc}
    \ce{O}\\
    ||\\
    \ce{\underset{\text{Diethyl ketone}}{H5C2 - C - C2H5}}
    \end{array}$

Mixed or unsymmetrical ketones: The ketones in which two alkyl groups bonded to carbonyl carbon are different are called mixed ketones or unsymmetrical ketones.
e.g.

  • $\begin{array}{cc}
    \ce{O}\phantom{..}\\
    ||\phantom{..}\\
    \ce{\underset{\text{Ethyl methyl ketone}}{H5C2 - C - CH3}}
    \end{array}$
  • $\begin{array}{cc}
    \ce{O}\phantom{.............}\\
    ||\phantom{.............}\\
    \ce{\underset{\text{Ethyl n-propyl ketone}}{H5C2 - C - CH2 -CH2 - CH3}}
    \end{array}$

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