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Write a note on halogenation of phenol.

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The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume:
SO2Cl2(g) $\rightarrow$SO2(g) + Cl2(g)
Experiment
Time/s–1
Total pressure/atm
1
0
0.4
2
100
0.7
Calculate the rate constant.
(Given: log4 = 0.6021, log2 = 0.3010).
Determine the formula for the half life of a first order reaction and prove that the half life of a first order reaction does not depends on the initial concentration of the reactant.
Complete the following chemical reaction equations:
$\text{Cr}_2\text{O}^{2-}_7(\text{aq})+\text{Fe}^{2+}(\text{aq})+\text{H}^+(\text{aq})\xrightarrow{\ \ \ \ \ \ \ \ \ }$
  1. For the complex [Fe(CN)6]3–, write the hybridization type, magnetic character and spin nature of the complex.

(At. number: Fe=26).

  1. Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL–1, then what shall be the molarity of the solution?
Mention a chemical property in which methanoic acid differs from acetic acid.
State the balance reaction equations of acidic permanganate ion with
(i) $Fe ^{2+}$
(ii) $C _2 O _4^{2-}$
(iii) $SO _3^{2-}$
Write overall cell reaction for lead storage battery when the battery is being charged.
How would you account for the following:
There is a gradual decrease in the atomic sizes of transition elements in a series with increasing atomic numbers.
Discuss the nature of bonding in metal carbonyls.